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Ramiel is surely immune to devil's traps, if he's not, he would be look at the devil's trap with his eyes, but he only saws Dean and the Winchesters didn't would be used holy oil and holy fire.
===[[12.12 Stuck in the Middle (With You)]]===
[[Sam]] spray paints a Devil's trap under the carpet, but the [[Prince of Hell]] [[Ramiel]] is able to avoid itjust walks right a cross. [[Dean]] also fires devil's trap bullets at Ramiel, which have no effect on him.
===[[12.23 All Along the Watchtower]]===
