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===[[9.17 Mother's Little Helper]]===
After [[Dean]] ignored a call from [[Sam]], [[Crowley]] remarks that he is lying to Sam is like Sam is Dean's wife, which would make him Dean's mistress.
===[[10.03 Soul Survivor]]===
After being [[Demon Cure|cured]] by [[Sam]] of from being a [[demon]], [[Dean]] asks [[Castiel]] if Sam wants a "divorce" after he had tried to kill him.
===[[10.05 Fan Fiction]]===